PSG has now won the season-opening trophy on fourteen separate times.
The Parisian giants required a dramatic leveler followed by a successful penalty shootout to get past Marseille in the Gulf and secure a fourth straight French Super Cup victory.
The European champions appeared to be coasting towards a comfortable win in the showdown featuring the French league champions and the French Cup winners after the French winger found the scoring early on.
However, Marseille fired two times in the closing moments to seize a shock advantage. Initially, the English forward converted from the penalty spot, before the defender inadvertently directed the ball into his own net for an own-goal.
In a remarkable twist of fortune, the Portuguese striker grabbed a crucial leveler in the dying moments to send the contest into a penalty shootout. The Parisian shot-stopper Chevalier then emerged as the key figure, stopping crucial attempts from O'Riley and Traore.
From the spot, Ramos, the midfielder, Nuno Mendes, and the young talent all converted successfully for PSG to complete a 4-1 penalty victory.
Now 14-time champions Paris Saint-Germain, who faced last season's Ligue 1 second-placed team Olympique de Marseille after completing a league and cup double, have now lifted this competition for the twelfth time in the past thirteen years.
